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SOLVED:A solution of 5-methyl-1 ,3-cyclopentadiene rearranges at room temperature to a mixture containing 1-methyl-, 2-methyl-, and 5-methyl-1 ,3-cyclopentadiene. (a) Show how both isomeric products are formed from the starting material by a sigmatropic rearrangement involving a C-H bond. (b) Explain why 2-methyl-1,3-cyclopentadiene is not formed directly from 5-methyl-1 ,3-cyclopentadiene by a (1 ,3] rearrangement.
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